The best lye for soap making is 99 percent pure, food-grade sodium hydroxide in pellet or bead form. Purity and food-grade ratings ensure the lye contains fewer impurities. Beads and pellets make it easier to measure. However, potassium hydroxide (not technically lye) is best for making liquid soap.
This article delves into the differences between sodium hydroxide and potassium hydroxide and lists the five best lyes for soap making. Toward the end, I’ll discuss where to purchase lye (aside from online retailers) and what safety precautions you should follow when working with the caustic substance.
Sodium Hydroxide vs. Potassium Hydroxide for Soap Making
Soap making initially involved wood ashes and animal fats, resulting in a mushy, dark-colored substance. Today, manufacturers use a similar process for liquid soaps, using potassium hydroxide and fats such as shea butter, coconut oil, and palm oil. For bar soap, however, companies utilize sodium hydroxide — also known as lye — as the primary ingredient.
Before jumping into the best types of lye for soap making, you must understand the difference between these two commonly used ingredients. No matter which chemical you choose, you’ll end up with a soap that lathers and cleans. However, each substance creates a different type of soap (solid bar soap and liquid soap) with its own look and feel.
Because of this, you must know which ingredient to use depending on the type of soap you intend to make.
Sodium hydroxide is true lye, also referred to as caustic soda. Its chemical name is NaOH. It’s the most common saponification ingredient used in soap making and results in a solid block of soap. Hardening happens due to the saponification process (when mixing lye with fat) because the substance crystallizes. Soap made using lye may be formed using molds or cut into bars or other shapes.
When purchasing sodium hydroxide, ensure that the product is 99 percent pure and in the form of pellets or beads. Purity ratings of 99 percent are essential because they ensure there are no unwanted additives.
Most soap makers prefer pellets or beads, as they’re easier to measure and produce far less dust. Static electricity often causes coarse powders or flakes to get everywhere, leading to a potentially dangerous situation, especially in homes with children or pets.
As an added note, food-grade lye is traditionally preferred for bar soap making. It undergoes an additional purification process, removing more impurities than technical-grade lye. With that said, technical-grade lye still works in soap making — it’s truly a matter of preference. Keep in mind that food-grade sodium hydroxide tends to be more expensive than the technical-grade version.
From a technical standpoint, potassium hydroxide (KOH) is not truly lye at all, nor do soap makers use it in the production of solid bar soap. If you attempt to use potassium hydroxide to make bar soap, you’ll end up with a gooey, sticky mess that doesn’t harden. Potassium hydroxide simply cannot create a solid product. Therefore, it’s only used in the production of liquid soaps and body washes.
As mentioned previously, early soap makers used ashes and animal fats. Interestingly, wood ashes produce potassium hydroxide, which is why potash creates more “authentic” soaps — meaning they’re closer to the original soaps made long ago.
Back then, soap makers often used salt to firm up the liquid, but it never formed the hardened blocks of soap you buy in stores. Today, some soap makers use hard fats to make bar soap with potassium hydroxide, but the curing time is significantly longer than with sodium hydroxide and the bars turn out softer. This is because potassium hydroxide does not crystallize.
When purchasing potassium hydroxide, look for products that mention food-grade to ensure you’re receiving a product with fewer impurities.
Best Lye Products for Soap Making
|Essential Depot Sodium Hydroxide||*Available in bulk|
*99 percent pure
|*Bottles aren’t vacuum sealed|
|ComStar Pure Lye||*Bead formula|
*99 percent pure
|*Not available in bulk|
*High price point for the amount
|Maxtite Sodium Hydroxide||*Available in bulk|
*Made in the US
*99 percent pure
|*High price point|
|Quality Chemical Sodium Hydroxide||*Available in bulk|
*99 percent pure
|Belle Chemical Potassium Hydroxide||*Available in bulk|
*Made in the US
|*90 percent pure|
1. Essential Depot Sodium Hydroxide
Due to the build-up of static electricity, sodium hydroxide flakes and powders tend to stick to their surroundings. Fortunately, the Essential Depot Sodium Hydroxide, available on Amazon, comes in evenly-sized pellets. As such, the product is less likely to cling to your surroundings and spread everywhere (thus, reducing the likelihood of dangerous situations).
Most soap makers also prefer pellets because they produce less dust and make measuring the product much easier with a food scale.
When purchasing Essential Depot Sodium Hydroxide, you’ll receive a bulk quantity of lye at a reasonable price point. Each order provides 32 pounds (14.51 kg) of sodium hydroxide. It arrives in 16 separate containers, each filled with two pounds (907 g) of the chemical. Some people find the multiple bottles inconvenient, whereas others prefer it for ease of use.
The plastic bottles come with child-resistant caps to prevent unwanted access. They’re resealable and BPA-free.
Essential Depot Sodium Hydroxide is food-grade, containing fewer impurities than other brands on the market. The color is pure white, making this an excellent choice for colored cold-process soaps, as it will not dilute or muddy your dyes.
2. ComStar Pure Lye
One of the best-selling soap-making products on the market, ComStar Pure Lye, offers industrial-strength sodium hydroxide with 99 percent purity. CornStar Pure Lye is pure white and therefore doesn’t dilute or mute colored soaps, allowing for more vibrant hues in the end product.
The solid lye comes in a spherical beaded formula, which most soap makers prefer over flakes or coarse powder. Beads, like pellets, make the sodium hydroxide much easier to measure out and work with. The beads rarely clump together the way that finer granules do.
This product is ideal for those who create soap in smaller batches. It comes in one-pound (454 g) containers. Because it’s not available in large quantities, purchasing a bulk amount of the ComStar Pure Lye tends to be a bit pricey.
3. Maxtite Sodium Hydroxide
The Maxtite Sodium Hydroxide, also available on Amazon, is 99 percent pure lye. As with all of the lye products included in this list, the Maxtite Sodium Hydroxide comes in beads, not flakes, powder, or granules. It’s pure white, making it ideal for dyed bars of soap.
It comes in a 40-pound (18 kg) tub. The sodium hydroxide arrives double-sealed, once in a plastic bag and again in the sealed plastic pail, to protect it from moisture. The product is manufactured in the United States.
4. Quality Chemical Sodium Hydroxide
The Quality Chemical Sodium Hydroxide (Available on Amazon) is the only technical-grade sodium hydroxide included on this list. Most soap makers prefer food-grade lye (due to the additional purification steps), and most manufacturers consider technical-grade sodium hydroxide perfectly suitable for soap making. It may not create a product as pure as food-grade lye, but it won’t affect the overall quality of the soap.
You’ll receive 40 pounds (18 kg) of caustic soda beads in a plastic pail for a reasonable price. It comes with a plastic bucket lid opener to make the container easier to open.
The one drawback to Quality Chemical Sodium Hydroxide is that it comes in an off-white color. It may not produce as vibrantly hued soaps as the pure white forms of lye.
5. Belle Chemical Potassium Hydroxide
Belle Chemical Potassium Hydroxide is the only potassium hydroxide formula on this list, particularly for liquid soap makers. It’s food-grade potash made in the United States, and it arrives in a durable, child-safe container.
It’s available in several package sizes, including:
- 1-pound (454 g)
- 2-pound (907 g)
- 5-pound (2 kg)
- 10-pound (4.5 kg)
- 20-pound (9 kg)
Unlike sodium hydroxide, the Belle Chemical Potassium Hydroxide does not harden, so it’s unsuitable for bar soap.
Where To Buy Lye for Soap Making
I’ve already listed four different types of lye and one type of potassium hydroxide for soap making, all of which are available on Amazon. In addition to online retailers, you can purchase lye in brick-and-mortar stores.
Below, I’ll provide other places where you can buy sodium hydroxide or potassium hydroxide for your soap-making needs.
Chemical Supply Companies
Most chemical supply companies carry sodium hydroxide and potassium hydroxide in bulk, usually in large bags, buckets, or bottles. Purchasing lye in bulk from chemical supply stores greatly reduces the price paid, especially compared to purchasing small batches from commercial retailers.
Because chemical supply stores typically only sell products in massive quantities of 40 pounds (18 kg) or more (usually for large manufacturing companies), you may end up with more lye than you can use in a year (one year is the shelf-life of caustic soda).
From small, locally-owned retailers to large corporate chains like Home Depot and Lowes, most hardware stores carry sodium hydroxide and potassium hydroxide. However, you won’t find the product in an aisle with other soap-making supplies. Instead, you’ll find it among the drain cleaners since caustic soda is often used to unclog drains and other plumbing fixtures.
When purchasing lye from a hardware store, check the ingredients to ensure you’re buying pure lye, not caustic soda with added ingredients. Some drain cleaners include other corrosive chemicals, such as hydrochloric acid, which you do not want to end up in your soap.
If you’re unable to find sodium hydroxide or potassium hydroxide in the store, reach out to a clerk. Some stores can place special orders for certain chemicals, especially when purchasing in bulk.
Other Brick-and-Mortar Stores
Chemical supply and hardware stores are the most likely brick-and-mortar locations to find lye. However, some soap makers can find sodium hydroxide and potassium hydroxide in craft stores, through homebrewing retailers, or in specialty-food markets.
In craft stores, lye is sold alongside other ingredients used in soap or candle making. Specialty-food stores sell hard-to-find food items and food-grade chemicals.
Since sodium hydroxide is used in many food applications, you may find it in these markets. Homebrewing retailers (who sell beer-brewing products) often sell food-grade lye for cleaning beer brewing equipment.
When purchasing lye through one of the abovementioned retailers, keep in mind that they’re unlikely to carry sodium hydroxide in bulk. More often, you’ll find it sold in small quantities for use in food, cleaning, or for making small batches of soap.
As such, you’ll end up paying more for the smaller bottles versus making a bulk purchase at a chemical supply company or hardware store.
Cautions When Using Lye for Soapmaking
While soap making sounds simple and relatively harmless, it involves the use of dangerous substances. Chemical reactions occur during the process, so it’s critical to know what you’re doing and not to blindly enter the world of soap-making.
Sodium hydroxide and potassium hydroxide are both caustic chemicals, meaning they’re corrosive. They can cause burns and even lead to severe or fatal injuries, especially if ingested. Additionally, when exposed to water, lye produces heat.
In some cases, the heat is enough to cause boiling. If improperly handled, the chemical may splatter, leading to injury.
When working with lye, you must wear proper protective gear, including:
- Long-sleeved shirt
Whenever you’re dealing with caustic chemicals such as sodium hydroxide, ensure that you’re free of distractions. That includes phone calls, children, pets, and even television shows. All of your attention should be solely focused on the soap-making task at hand to avoid mix-ups, improper measurements, or other dangerous mistakes.
In addition, you must store your lye in an area away from children, pets, and moisture. If storing with other substances, ensure that they’re alkali-resistant chemicals. Also, ensure that the container of lye is tightly sealed. When exposed to carbon dioxide, sodium hydroxide may convert to sodium carbonate.
For more, check out Can You Make Soap Without Lye? | Yes and No.
Hi, I’m Anne but my grandchildren call me Jelly Grandma. I have over 50 years of experience as a Southern cook and am a retired librarian. I love sharing what I have learned. You can find me on YouTube as well! Just click the link at the bottom of your page.
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